|
|
(3S,6S)-6-Isopropenyl-3-methyl-2-oxo-oxepanone + H2O <=> (5S)-6-Hydroxy-5-isopropenyl-2-methylhexanoate + H+
|
3.1.1.83
monoterpene epsilon-lactone hydrolase
|
–
|
| |
KEGG:
R06393
MetaCyc:
RXN-9432
|
|
|
|
4-isopropenyl-7-methyloxepan-2-one + H2O <=> H+ + (3S,6R)-6-hydroxy-3-isopropenyl-heptanoate
|
3.1.1.83
monoterpene epsilon-lactone hydrolase
|
–
|
| |
MetaCyc:
RXN-9421
|
|
|
|
(3S)-3-isopropenyl-6-oxoheptanoate + CoA + ATP <=> (3S)-3-Isopropenyl-6-oxoheptanoyl-CoA + ADP + phosphate
|
6.2.1
|
–
|
| |
MetaCyc:
RXN-9423
|
|
|
|
(+)-dihydrocarveol + NAD+ <=> (-)-dihydrocarvone + NADH + H+
|
1.1.1.198
(+)-borneol dehydrogenase
1.1.1.296
dihydrocarveol dehydrogenase
|
–
–
|
| |
BRENDA:
BS187487
KEGG:
R06383
MetaCyc:
RXN-9429
|
|
|
|
(1R,4S)-isodihydrocarvone <=> (-)-dihydrocarvone
|
not assigned
|
–
|
| |
KEGG:
R06381
MetaCyc:
RXN-9428
|
|
|
|
(1S,2S,4R)-iso-dihydrocarveol + NAD+ <=> (1R,4S)-isodihydrocarvone + NADH + H+
|
1.1.1.296
dihydrocarveol dehydrogenase
|
–
|
| |
KEGG:
R06377
MetaCyc:
RXN-9426
|
|
|
|
(3S,6R)-6-hydroxy-3-isopropenyl-heptanoate + NAD+ <=> H+ + (3S)-3-isopropenyl-6-oxoheptanoate + NADH
|
not assigned
|
–
|
| |
MetaCyc:
RXN-9422
|
|
|
|
(1R,2S,4R)-neo-dihydrocarveol + NAD+ <=> (1R,4S)-isodihydrocarvone + NADH + H+
|
1.1.1.296
dihydrocarveol dehydrogenase
|
–
|
| |
KEGG:
R06379
MetaCyc:
RXN-9425
|
|
|
|
(1R,4S)-isodihydrocarvone + NADPH + H+ + O2 <=> 4-isopropenyl-7-methyloxepan-2-one + NADP+ + H2O
|
1.14.13.105
monocyclic monoterpene ketone monooxygenase
|
–
|
| |
KEGG:
R06387
MetaCyc:
RXN-9420
|
|
|
|
(2S,4S)-carveol + mycofactocinone <=> (S)-carvone + mycofactocinol
|
1.1.98
|
–
|
| |
MetaCyc:
RXN-9401
|
|
|
|
(1R,4S)-isodihydrocarvone + acceptor <=> (S)-carvone + reduced_acceptor
|
1.3.99.25
carvone reductase
|
–
|
| |
BRENDA:
BR48903
KEGG:
R06372
MetaCyc:
RXN-9419
|
|
|
|
(1S,2R,4R)-neoisodihydrocarveol + NAD+ <=> (-)-dihydrocarvone + NADH + H+
|
1.1.1.296
dihydrocarveol dehydrogenase
|
–
|
| |
KEGG:
R06385
MetaCyc:
RXN-9430
|
|
|
|
(+)-trans-carveol + NAD+ <=> (S)-carvone + NADH + H+
|
1.1.1.275
(+)-trans-carveol dehydrogenase
|
–
|
| |
BRENDA:
BR47616
KEGG:
R06117
MetaCyc:
RXN-9397
|
|
|
|
(-)-dihydrocarvone + O2 + NADPH + H+ <=> (3S,6S)-6-Isopropenyl-3-methyl-2-oxo-oxepanone + H2O + NADP+
|
1.14.13.105
monocyclic monoterpene ketone monooxygenase
|
–
|
| |
KEGG:
R06389
MetaCyc:
RXN-9431
|
|
